• 专利附录
  • 专利说明
  • 权利要求
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    • 专利摘要:
    FLUID BED REACTOR, APPARATUS FOR REGENERATING REACTION, PROCESS FOR PREPARING OLEFINS AND PROCESS FOR PREPARING AROMATIC HYDROCARBONS The present invention relates to a fluidized bed reactor, comprising an inlet zone in a lower position, an outlet zone in a highest position and a reaction zone between the entry zone and the exit zone. A guide plate with hollow holes is arranged in the reaction zone, comprising a dense channel region at an intermediate region thereof and a sparse channel region disposed at a periphery thereof and encompassing the dense channel region. The catalysts in said fluidized delight reactor can be distributed homogeneously in its reaction zone, whereby the efficiency of the reaction can be improved. A reaction regeneration apparatus comprising said fluidized bed reactor, and a process for preparing olefins from oxygenates and a process for preparing aromatic hydrocarbons from oxygenates using the reaction regeneration apparatus. Figure 1
    公开号:BR102015026091B1
    申请号:R102015026091-1
    申请日:2015-10-14
    公开日:2022-02-15
    发明作者:Weimin Yang；Xiaohong Li；Siqing Zhong；Guozhen Qi；Jun Xu；Zhinan Yu
    申请人:China Petroleum & Chemical Corporation；Shanghai Research Institute Of Petrochemical Technology Sinopec；
    IPC主号:
    专利说明:

    CROSS REFERENCE WITH RELATED ORDER
    [001] The present application claims the benefit of Chinese patent application CN 201410539938.0 entitled Multiregion Coupling Reinforcing Process for Preparing Olefins from Methanol and filed on October 14, 2014, the entirety of which is incorporated herein by reference. FIELD OF TECHNIQUE
    [002] The present disclosure relates to the field of chemical engineering technique, and in particular to a fluidized bed reactor. The present disclosure further relates to a reaction regeneration apparatus for use in a fluidized bed reactor, and to a process for preparing olefins and a process for preparing aromatic hydrocarbons. FUNDAMENTALS OF THE INVENTION
    [003] In modern petrochemical engineering, ethylene and propylene are the most crucial basic materials. Ethylene can be used in the preparation of downstream products including polyethylene, styrene, vinyl acetate, ethylene oxide and ethylene glycol and so on. Propylene can be used in the preparation of downstream products including polypropylene, acrylonitrile, propylene oxide and isopropyl alcohol and so on. Ethylene and propylene and their downstream products are widely used in the fields of industry and agriculture, transport and national defense.
    [004] In recent years, demand for ethylene and propylene remains high. Under the circumstance that the oil resource gradually diminishes, the short oil supply in China can be greatly alleviated through coal chemical technology, with which ethylene and propylene can be prepared from non-oil resources. This is significant in promoting the development of the national heavy chemical industry. Based on coal chemical technology, oxygenates can be prepared from coal and then olefins can be prepared from oxygenates.
    [005] At present, an apparatus for preparing olefins from methanol is similar to a catalytic cracking device, both being of the continuous reaction regeneration type. According to patent literature US166282, a process and a reactor for converting oxides to low carbon olefins are disclosed. A fast fluidized bed reactor is used in a technical solution from the patent literature above. The gas reacts in a reaction zone with low gas velocity and then rises to a fast separation zone with rapidly decreasing internal diameter. The catalysts loaded into the product are separated through a preliminary cyclone. Because the product and catalysts are quickly separated, the secondary reaction can be effectively prevented. The reactor used in the above patent literature is an upflow fast fluidized bed reactor with a traditional feed inlet.
    [006] Chinese patent literature CN103121901A recites a method for converting oxygenated chemicals to generate low carbon olefins. According to the above method, the catalysts that will be generated and the catalysts regenerated are pre-mixed in a catalyst mixer and then entered into a reactor, so the problems of insufficient mixing of catalysts and small production of low olefins content carbon in a reaction zone in the prior art can be resolved.
    [007] Chinese patent literature CN101164685A refers to a combined fast fluidized bed reactor for oxygenates or catalytic reaction of dimethyl ether. According to the above patent literature, a separation device in a settling zone is arranged externally, so that the space occupied by the settler can be reduced, thereby the settling speed of the catalysts can be increased and the settling time can be increased. permanence of olefins can be reduced. In the meantime, problems of low selectivity and low production of ethylene and propylene can also be solved. When compared with a traditional fast fluidized bed reactor comprising an external sedimenter, the production of ethylene can be increased by 4% and that of propylene can be increased by 3%.
    [008] In the prior art, the concentration distribution of the catalyst particles in the fluidized bed reactor is not uniform, but preferably presents characteristics of distribution of dilute concentration at the top of the fluidized bed reactor and dense concentration at its bottom and the dilute concentration in its intermediate region and the dense concentration in its peripheral sections. The above distribution characteristics severely influence the reaction efficiency, therefore, they urgently require improvement. SUMMARY OF THE INVENTION
    [009] Directed against the above problem, a fluidized bed reactor is provided in accordance with the present disclosure. The catalysts can be distributed homogeneously in a reaction zone of the fluidized bed reactor in accordance with the present disclosure, whereby the efficiency of the reaction can be improved. The present disclosure further relates to a reaction regeneration apparatus comprising said fluidized bed reactor, a process for preparing olefins from oxygenates and a process for preparing aromatic hydrocarbons from oxygenates using the reaction regeneration apparatus. .
    [010] In a first aspect according to the present disclosure, a fluidized bed reactor is provided, comprising an inlet zone at a lower position, an outlet zone at a higher position and a reaction zone between the zone input and output zone. A guide plate is disposed in the reaction zone, comprising a dense channel region at an intermediate region thereof and a sparse channel region disposed at a periphery thereof encompassing the dense channel region.
    [011] In the fluidized bed reactor according to the present disclosure, the dense channel region has a relatively large obstacle to material moving upwards, while the sparse channel region has relatively little obstacle in it. Therefore, especially when the reaction material is gas, in the reaction zone of the fluidized bed reactor, the pressure drop of the gas in an intermediate region is relatively large and that in the surrounding regions is relatively small. Under the guide plate in the fluidized bed reactor, the gas in the intermediate region will be forced to the peripheral regions, so the velocity of the gas flowing through the sparse channel region can be increased. In that case, above the guide plate, the gas velocity of the marginal regions of the circumference of the fluidized bed reactor will be increased, whereby catalyst particles in the marginal regions of the circumference can be blown upwards. Under the influence of a fluidized bed reactor wall and the general material flow in the fluidized bed reactor, the upward blown catalyst particles flow to the intermediate region of the reaction zone. As a result, the catalyst particles can be homogeneously distributed along the radial direction of the fluidized bed reactor, whereby the reaction efficiency can be improved.
    [012] In an embodiment according to the present disclosure, the dimension of a channel in the dense channel region is smaller than the dimension of the channel in the sparse channel region. Preferably, the ratio of the channel dimension in the dense channel region to that of the channel in the sparse channel region is in the range of 1:4 to 2:3. Preferably, the channel dimension in the dense channel region is in a range of 0.01 to 0.08 m. This is because in the fluidized bed reactor, the size of a single bubble can vary according to the diameter of the fluidized bed reactor. Under general conditions, the bubble size is not more than 0.12 m. In this case, the bubbles of the reaction mass and the aggregates of the catalyst particle in the fluidized bed reactor will be disrupted. Therefore, the homogeneity of the mixture of reaction mass and catalysts can be increased and the contact area between the reaction mass and catalysts can be increased, whereby the efficiency of the reaction can be further improved.
    [013] In one embodiment, each of the dense channel region and the sparse channel region comprises a circular plate having equally distributed pores, or a plurality of concentric ring-shaped angled panels or a plurality of straight panels separated in parallel. The guide plate of these types can create the gas flow, so that the homogeneity of catalyst distribution in a radial direction can be further improved.
    [014] In one embodiment, the dense channel region is round in shape and the sparse channel region is ring-shaped, and the ratio of the diameter of the dense channel region to the width of the sparse channel region is at a range from 2:1 to 9:1. In that case, the guide plate can be easily mounted on the fluidized bed reactor.
    [015] In one embodiment, a plurality of guide plates distributed along the axial direction of the fluidized bed reactor are provided. By arranging a plurality of guide plates, the homogeneity of catalyst distribution in the radial direction of the fluidized bed reactor can be further increased, and reaction mass bubbles and catalyst particle aggregates can be more easily disrupted. As a result, the efficiency of the reaction can be further improved.
    [016] In one embodiment, the inlet for the accelerator gas is arranged in the outlet zone of the fluidized bed reactor. Preferably, the inlet for the accelerator gas is configured to extend obliquely from a lower to a higher position. In this case, gas such as nitrogen, inert gas or water vapor, which has a high velocity, can be injected into the outlet zone of the fluidized bed reactor through the inlet to the accelerating gas, so that the pressure in the reactor is fluidized bed can be more uniform and the catalysts can be more evenly distributed in the fluidized bed reactor. In that case, the defect of the fluidized bed reactor in the prior art that the density of catalysts at the top of the fluidized bed reactor is relatively small, while the density of catalysts at its bottom is relatively large, can be eliminated. Together, by arranging the inlet for the accelerator gas, the catalysts can spread homogeneously along the axial direction of the fluidized bed reactor, so that the efficiency of gas-solid contact can be optimized. In the meantime, the circulation rate of the catalysts throughout the reaction regeneration apparatus can be improved and the product yield can be increased.
    [017] In one embodiment, the inlet to the accelerator gas forms an angle in a range of 5 to 39 degrees in relation to the longitudinal axis of the fluidized bed reactor. In another embodiment, the ratio of the diameter of the inlet for the accelerator gas to a diameter of the outlet zone of the fluidized bed reactor is in a range of 0.01 to 0.1. In a further embodiment, the ratio of the length of the portion of the fluidized bed reactor outlet zone that lies above the inlet for the accelerator gas to an overall length of the fluidized bed reactor outlet zone is in a range of 0.1 at 0.8.
    [018] In a second aspect of the present disclosure, a reaction regeneration apparatus is provided, comprising said fluidized bed reactor and further comprising a separation device and a catalyst regeneration device respectively connected with the fluidized bed reactor. The separation device comprises a preliminary gas and solids separator in communication with an outlet zone of the fluidized bed reactor; a vertically arranged draft damper, a lower region of the draft damper being in communication with a solids outlet of the preliminary gas and solids separator to collect catalyst particles, and a higher region of the draft damper being in communication with an outlet of gas from the preliminary gas and solids separator and a fine gas and solids separator, an inlet of the fine gas and solids separator in communication with the upper region of the draft damper and its solids outlet in communication with the lower region of the draft damper. The catalyst regeneration device comprises a feed zone in a lower position and a discharge zone in a higher position, the feed zone being arranged lower than the lowest region of the draft damper and the discharge zone being arranged higher than the inlet zone of the fluidized bed reactor. The lower region of the draft damper is in communication with the feed zone of the catalyst regeneration device through a second pipe, and the discharge zone of the catalyst regeneration device is in communication with the inlet zone of the reactor. fluidized bed through a third pipe.
    [019] The catalysts transported in the fluidized bed reactor product can be quickly separated through the preliminary gas and solids separator and the fine gas and solids separator, so the secondary reaction of the product under the catalysis of the catalysts that will be regenerated that are still active can be effectively prevented. Production efficiency can also be greatly increased due to quick separation. In addition, fluidized bed reactor product generally has high velocity, thereby impacting the device receiving the product at high velocity to the extent of intense vibration. As a result, the device can even get damaged. According to the present disclosure, a draft damper is arranged between the preliminary gas solids separator and the fine gas solids separator, so that the high velocity product impact can be absorbed by the preliminary gas solids separator. and the draft damper together, whereby damage to the entire separating device can be prevented. It is unnecessary for the preliminary gas and solids separator and draft damper to be manufactured large.
    [020] In one embodiment, the diameter of the highest region of the draft damper is smaller than that of its lowest region. Preferably, the ratio of the diameter of the higher region to that of the lower region is in a range of 0.05 to 0.5. The fluctuation caused by the product flowing rapidly from the fluidized bed reactor to the upper region of the draft damper can be quickly reduced by the higher region with smaller diameter, so that the lower region of the draft damper can remain in a relatively placid. As a result, the catalysts can be stably accommodated in the lower region of the draft damper and the gas and solids separation efficiency can be improved.
    [021] In one embodiment, the lower region of the draft damper is configured and arranged so that it performs a steam withdrawal operation. For example, the steam inlet may be disposed at a lower end of the draft damper and the structure or component for use in a steam withdrawal operation may be disposed within the lower region of the draft damper. The structure or component is well known to the person skilled in the art. Water vapor is fed to the lower region of the draft damper through its lower end, so that the product loaded on the catalysts can be separated from the catalysts. The separated product rises with the water vapor to the uppermost region of the draft damper and mixes with the product therein. In that case, the yield of the product can be greatly increased. Furthermore, as described above, the draft damper is configured so that severe fluctuation in its lower region can be prevented, thereby facilitating the steam withdrawal operation.
    [022] In one embodiment, the position where the gas outlet of the preliminary gas and solids separator is connected to the draft damper is below a position where the inlet of the fine gas and solids separator is connected to the draft damper. . Based on the above configuration, the catalysts loaded into the product can be precipitated as the product flows up the draft damper, which further increases the gas and solids separation efficiency.
    [023] In one embodiment, the preliminary gas and solids separator is a cyclone separator, and the fine gas and solids separator comprises two-stage or multi-stage cyclone separators. Two-stage or multi-stage series cyclone separators are configured so that the inlet of a first stage cyclone separator is in communication with the uppermost region of the draft damper, the product being obtained from a gas outlet of a last stage cyclone separator, a gas outlet of an upstream cyclone separator is in communication with an inlet of an adjacent downstream cyclone separator, and the solids outlets of all cyclone separators are in communication with the region lower end of the draft damper. Additionally, the separating effect of product catalysts can be improved by multiple cyclone separators in series connection. As a result, the catalyst recovery efficiency can be improved and the product obtained can contain less impurities. The cyclone separator can facilitate quick separation of catalysts from the product and has the advantages of simple structure and low price. In a preferred embodiment, both the preliminary gas solids separator and the fine gas solids separator are cyclone separators.
    [024] In one embodiment, the uppermost region of the draft damper is provided with an inlet orifice for communication with the gas outlet of the preliminary gas and solids separator and the inlet orifice configured to be tangent to a side wall of the highest region. Product from the fluidized bed reactor may be fed into the uppermost region of the draft damper through said inlet orifice on a path that is tangent to the sidewall of its uppermost region. As a result, the impact of the product on the draft damper can be reduced, so that the vibration of the draft damper can be alleviated. In addition, the rotating product can also facilitate the precipitation of catalysts therein, thereby further improving the efficiency of gas and solids separation.
    [025] In one embodiment, the third barrel is provided with a flow-blocking member at the top of its inner wall. The flow blocking member is used to block the gas and catalysts flowing back into the third pipe caused by the strong reaction in the fluidized bed reactor. In that case, the feed rate of catalyst particles can be effectively increased, so that the circulating rate of catalysts can be further increased, whereby the product yield can be increased.
    [026] In an embodiment according to the present disclosure, the flow blocking member is an inclined baffle for the fluidized bed reactor. In one specific example, the ratio of the baffle area to the cross-sectional area of the third barrel is in a range of 0.1 to 1. The baffle is either sector or rectangular in shape. The ratio of the distance between the deflector and the fluidized bed reactor to the length of the third pipe is in a range of 0.01 to 0.5. The angle formed between the deflector and the axis of the third barrel is in a range of 10 to 75 degrees. Preferably, a plurality of deflectors arranged in parallel with respect to each other are provided.
    [027] In another embodiment, the flow blocking member is a radially inwardly projecting stop pawl. Preferably, a plurality of pawls arranged in a row along the axis of the third barrel are provided. In one embodiment, the ratio of the length of each pawl to the diameter of the third barrel is in a range of 0.1 to 0.5. Preferably, the cross section of each of the stop tabs is in the shape of a triangle, a rectangle or a sector.
    [028] In one embodiment, the inlet zone of the fluidized bed reactor is arranged lower than the lower region of the draft damper and the lower region of the draft damper is in communication with the inlet zone of the draft reactor. fluidized bed through a first pipe. This apparatus can be used to prepare olefins from methanol.
    [029] In one embodiment, each of the first pipe, the second pipe and the third pipe is provided with a valve to control the flow of material.
    [030] In a third aspect according to the present disclosure, a process for preparing olefins is proposed, using said reaction regeneration apparatus. The inlet zone of the fluidized bed reactor is arranged lower than the lowest region of the draft damper of a separation device, and the lower region of the draft damper is in communication with the inlet zone of the bed reactor. fluidized through a first pipe. The process comprises the steps of: reacting the raw material containing oxygenates with catalysts in a reaction zone of the fluidized bed reactor; feeding the obtained product and loaded catalysts into the separation device through an outlet zone of the fluidized bed reactor; separating the product from the loaded catalysts through the separation device, feeding a portion of the catalysts obtained from the separation directly into the inlet zone of the fluidized bed reactor and regenerating the remaining catalysts and feeding the regenerated catalysts into the inlet zone of the reactor bed reactor and mixing the unregenerated catalysts and the regenerated catalysts in the inlet zone of the fluid bed reactor and then feeding the mixed catalysts into the reaction zone of the fluid bed reactor.
    [031] In an embodiment according to the present disclosure, the weight ratio of unregenerated catalysts to regenerated catalysts is in a range of 0.3 to 1.5.
    [032] In one embodiment, the operation of the separation device comprises the following steps. The product from the fluidized bed reactor having catalysts loaded therein is preliminarily separated through a preliminary gas and solids separator. The product obtained from the preliminary separation carrying the remaining catalysts is fed into the uppermost region of the draft damper. The product is then removed from the draft damper and fed into a fine gas and solids separator for fine separation. Subsequently, the product is obtained from a gas outlet of the fine gas and solids separator and the catalysts from the preliminary gas and solids separator and the fine gas and solids separator are collected in the lower region of the draft damper.
    [033] In an embodiment according to the present disclosure, water vapor is fed into the draft damper from its lower end, so that the product loaded on the catalysts can be separated from the catalysts.
    [034] In an embodiment according to the present disclosure, the pressure in the fluidized bed reactor by the gauge pressure is in a range of 0 to 0.4 MPa, the average temperature therein is in a range of 380 to 550°C and the average density in the reaction zone is in a range of 40 to 200 kg/m3. The catalyst used in it is SAPO-34, a catalyst regeneration medium with air and regeneration temperature being in a range of 600 to 700°C.
    [035] In one embodiment, the ratio of the pressure drop generated when the gaseous feedstock flows through the dense channel region to that generated when the gaseous feedstock flows through the sparse channel region is in a range of 1, 2:1 to 10:1.
    [036] In one embodiment, the inlet for the accelerating gas is arranged at the outlet zone of the fluidized bed reactor, and the gas flowing into the outlet zone of the fluidized bed reactor through the inlet for the accelerating gas is steam. water or nitrogen, the linear velocity of the gas being in a range of 1.0 to 10.0 m/s.
    [037] In one embodiment, the oxygenates comprise one or more selected from a group consisting of methanol, ethanol, n-propyl alcohol, isopropyl alcohol, C4-C20 alcohol, ethyl methyl ether, dimethyl ether, diethyl ether, diisopropyl ether, methanol , dimethyl carbonate, acetone and acetic acid and the weight of the oxygenates is responsible for 10 to 100% of the raw material.
    [038] In a fourth aspect according to the present disclosure, a process for preparing aromatic hydrocarbons is proposed, using said reaction regeneration apparatus. The process comprises: reacting raw material containing oxygenates with catalysts in a reaction zone of a fluidized bed reactor; feeding the product obtained and the catalysts loaded into a separation device through an outlet zone of the fluidized bed reactor and separating the product from the catalysts loaded therein through the separation device, regenerating the catalysts obtained from the separation and feeding the catalysts regenerated into the inlet zone of the fluidized bed reactor and into the reaction zone of the fluidized bed reactor.
    [039] In one embodiment, the operation of the separation device comprises the following steps. The product from the fluidized bed reactor having the catalysts loaded therein is preliminarily separated through a preliminary gas and solids separator. The producer obtained from the preliminary separation carrying the remaining catalysts is fed into the uppermost region of the draft damper. The product is then removed from the draft damper and fed into a fine gas and solids separator for fine separation. Subsequently, the product is obtained from a gas outlet of the fine gas and solids separator and the catalysts from the preliminary gas and solids separator and the fine gas and solids separator are collected within the lower region of the draft damper.
    [040] In one embodiment, water vapor is fed into the draft damper from its lower end, so that product loaded onto the catalysts can be separated from the catalysts.
    [041] In one embodiment, the pressure in the fluidized bed reactor by the gauge pressure is in a range of 0 to 0.6 MPa, the average temperature in it is in a range of 440 to 550°C, the space velocity in the zone of reaction ranges from 0.3 to 5 h-1 and the average density in the reaction zone ranges from 200 to 450 kg/m3. The catalyst used in it is ZSM-5, the catalyst regeneration medium being air and the regeneration temperature in a range of 550 to 650°C.
    [042] In one embodiment, the pressure drop generated when the gaseous feedstock flows through the dense channel region to that generated when the gaseous feedstock flows through the sparse channel region is in a range of 1.2: 1 to 10:1.
    [043] In one embodiment, the inlet to the accelerator gas is disposed at the outlet zone of the fluidized bed reactor, and the gas flowing into the outlet zone of the fluidized bed reactor through the inlet to the accelerant gas is steam. water or nitrogen, the linear velocity of the gas being in a range of 1.0 to 10.0 m/s.
    [044] In one embodiment, the oxygenates comprise one or more selected from a group consisting of methanol, ethanol, n-propyl alcohol, isopropyl alcohol, C4-C20 alcohol, ethyl methyl ether, dimethyl ether, diethyl ether, diisopropyl ether, methanol , dimethyl carbonate, acetone and acetic acid and the weight of the oxygenates is responsible for 10 to 100% of the raw material.
    [045] When compared to the prior art, the present disclosure has the following advantages. A guide plate is arranged in the fluidized bed reactor according to the present disclosure, so that the catalysts therein can be distributed homogeneously, whereby the efficiency of the reaction can be improved. Additionally, the reaction regeneration apparatus according to the present disclosure not only has high reaction efficiency, but also high gas and solids separation efficiency. As a result, product yield can also be increased. BRIEF DESCRIPTION OF THE DRAWINGS
    [046] The present disclosure will be further described in detail based on the examples in view of the accompanying drawings. In the drawings: Figure 1 schematically shows a structure of a fluidized bed reactor according to an example of the present disclosure, Figure 2 shows a space diagram of a guide plate according to example 1 of the present disclosure, Figure 3 shows a sectional view of AA in figure 2, figure 4 shows a space diagram of a guide plate according to example 2 of the present disclosure, figure 5 shows a space diagram of a guide plate according to with example 3 of the present disclosure, Figure 6 schematically shows a structure of a fluidized bed reactor comprising a plurality of guide plates according to an example of the present disclosure, Figure 7 schematically shows a reaction regeneration apparatus according to with example 1 of the present disclosure, Figure 8 schematically shows a separation device for use in the fluidized bed reactor according to example 1 of the present disclosure, Figure 9 shows and schematically a separation device for use in the fluidized bed reactor according to example 2 of the present disclosure, Figure 10 shows an enlarged view of section A in Figure 7 according to an example of the present disclosure, Figure 11 shows a view enlarged view of section A in Figure 7 according to another example of the present disclosure and Figure 12 schematically shows a reaction regenerating apparatus according to example 2 of the present disclosure.
    [047] In the drawings, the same components are indicated with the same reference sign. Drawings are not drawn to full scale. DETAILED DESCRIPTION OF MODALITIES
    [048] The present disclosure will be further described in view of the accompanying drawings.
    [049] Figure 1 schematically shows a fluidized bed reactor 4 according to an example of the present disclosure. As shown in figure 1, the fluidized bed reactor 4 comprises an inlet zone 70 in a lower position, an outlet zone 42 in a higher position and a reaction zone 41 between the inlet zone 70 and the outlet 42. A guide plate 48 is arranged in the reaction zone 41.
    [050] A plurality of guide plates 48 may be provided distributed along the axial direction of the fluidized bed reactor 4, as shown in figure 6. It should be understood that figure 6 merely schematically shows the reaction zone 41 of the fluidized bed reactor 4 and two guide plates 48 arranged in the reaction zone 41. In fact, the number of guide plates 48 can be one, two or more based on the actual situation.
    [051] The guide plate 48 can be used in the reaction zone 41 of the fluidized bed reactor, so that the catalyst particles can be more homogeneously distributed in a radial direction. The guide plate 48 comprises a dense channel region 61 disposed in an intermediate region thereof and a sparse channel region 62 disposed at a periphery thereof encompassing the dense channel region 61. The dense channel region 61 has relatively large material obstacle. moving upwards, while the sparse channel region 62 has relatively little obstacle to it. Under the guide plate 48 in the fluidized bed reactor 4, the gas in the intermediate region will be forced to flow to the surrounding regions, so that the velocity of the gas flowing through the sparse channel region 62 can be increased. In that case, above the guide plate 48, the gas velocity in the marginal regions of the circumference of the fluidized bed reactor 4 will be increased, whereby the catalyst particles in the marginal regions of the circumference can be blown upwards. Under the influence of a wall of the fluidized bed reactor 4 and a general material flow in the fluidized bed reactor 4, the catalyst particles blown upwards flow to an intermediate section of the reaction zone 41 of the fluidized bed reactor 4 (the Figure 6 schematically shows the gas flow directions with arrows). As a result, the catalyst particles in the reaction zone 41 of the fluidized bed reactor 4 can be more homogeneously distributed in the radial direction, rather than being diluted in the medium while being coarse in the surrounding regions.
    [052] Guide plate 48 is normally round in shape. The dense channel region 61 is round-shaped and the sparse channel region 62 is annular-ring-shaped. The ratio of the diameter of the dense channel region 61 to the width of the sparse channel region 62 is in a range of 2:1 to 9:1, which can facilitate the mounting of the guide plate 48 in the fluidized bed reactor 4. Because it is necessary for the sparse channel region 62 to be engaged with a wall of the fluidized bed reactor 4, an appropriate width of the sparse channel region 62 can make the assembly operation easier.
    [053] The dimension of the channel in the dense channel region 61 is smaller than the dimension of the channel in the sparse channel region 62. For example, the ratio of the dimension of the channel in the dense channel region 61 to that of the channel in the region of sparse channel 62 is in a range of 1:4 to 2:3. Preferably, the dimension of the channel in the dense channel region 61 is in a range of 0.01 to 0.08 m. In this case, the reaction mass bubbles and the catalyst particle aggregates in the fluidized bed reactor 4 will be disrupted. Therefore, the mixing homogeneity between the reaction mass and the catalysts can be increased, and the contact area between the reaction mass and the catalysts can be increased, whereby the reaction efficiency can be further improved.
    [054] Figures 2, 3, 4 and 5 respectively show multiple shapes of the guide plate 48. As shown in Figures 2 and 3, the dense channel region 61 comprises a plurality of separate concentric ring-shaped plates. The space 66 between adjacent concentric ring-shaped plates 65 forms a channel. The sparse channel region 62 comprises straight panels 67 which are spaced apart and arranged substantially along the radial directions of the guide plate 48 in parallel. The space 68 between adjacent straight panels 67 forms a channel. In one example, each of the plurality of concentric ring-shaped plates 65 is configured to slant outward with respect to a horizontal direction from the center of a circle and each of the plurality of straight panels 67 is configured to slant with respect to the center of a circle. to the horizontal direction. For example, a tilt angle can be in a range of 45 to 85 degrees.
    [055] As shown in Figure 4, both the channel in the dense channel region 61 and the channel in the sparse channel region 62 are square holes and the dimension of the square hole in the dense channel region 61 is smaller than that of the square hole. in the sparse channel region 62. For example, the ratio of the dimension of the square hole in the dense channel region 61 to that of the square hole in the sparse channel region 62 can range from 1:4 to 2:3. It should be understood that the shape of the channel is not limited to the square hole, it can also be a round hole, an elliptical hole or a hole of any other type.
    [056] As shown in Figure 5, the dense channel region 61 comprises a plurality of parallel-spaced straight panels 69 and the space 80 between adjacent straight panels forms a channel. The sparse channel region 62 comprises straight panels 81 which are spaced apart and arranged substantially along radial directions of the guide plate 48 in parallel and the space 82 between adjacent straight panels forms a channel. In one example, each of the plurality of straight panels 69 is configured to slant outward with respect to a horizontal direction from a center of a circle, and each of the plurality of straight panels 81 is configured to slant with respect to the horizontal. For example, the tilt angle can be in the range of 45 to 85 degrees.
    [057] The inlet 49 for the accelerator gas is arranged in the outlet zone 42 of the fluidized bed reactor 4. Preferably, the inlet 49 for the accelerator gas is configured to extend obliquely from a lower position to a lower position. taller. In that case, the gas having high velocity can be injected into the outlet zone 42 of the fluidized bed reactor 4 through the inlet 49 for the accelerator gas, so that the pressure in the fluidized bed reactor 4 can be more uniform, and the catalysts can be distributed more evenly in the fluidized bed reactor 4. As a result, the product yield can also be higher. The inlet 49 for the accelerator gas forms an angle in a range of 5 to 39 degrees with respect to a vertical direction (i.e. the longitudinal axis of the fluidized bed reactor 4), for example the angle may be 10 or 15 degrees. The diameter of the inlet 49 for the accelerator gas is smaller than that of the outlet zone 42. For example, the ratio of the diameter of the inlet 49 for the accelerator gas to that of the outlet zone 42 can be 0.05 or 0.1 . The ratio of the length L1 of a part of the outlet zone 42 of the fluidized bed reactor 4 which lies above the inlet 49 for the accelerator gas to an overall length L2 of the outlet zone 42 of the fluidized bed reactor 4 is in a range of 0.1 to 0.8. For example, the ratio might be 0.1 or 0.4.
    [058] Figure 7 schematically shows a reaction regeneration apparatus 30 in accordance with example 1 of the present disclosure. As shown in Figure 7, the reaction regeneration apparatus 30 comprises a separation device 10, the fluidized bed reactor 4 and a catalyst regeneration device 50, as well as pipes for connecting the separation device 10, the bed reactor fluidized 4 and the catalyst regeneration device 50.
    [059] The outlet zone 42 of the fluidized bed reactor 4 is in communication with the preliminary gas and solids separator 7 of the separation device 10. The raw material and catalysts react in the reaction zone 41 and generate the product. The product loads the partial catalysts and leaves the fluidized bed reactor 4 through the outlet zone 42.
    [060] The catalyst regeneration device 50 comprises a feed zone 51 in a lower position and a discharge zone 52 in a higher position. The catalyst regeneration device 50 is used to reactivate catalysts that are spent in the fluidized bed reactor 4 and have lost activity.
    [061] As shown in Figure 8, the separation device 10 according to example 1 of the present disclosure is generally used together with the fluidized bed reactor 4. Specifically, the separation device 10 is configured to receive the product having catalysts. loaded into it from a product outlet 12 of the fluidized bed reactor 4. After the product flows through the separation device 10, the catalysts loaded into it are separated therefrom. The separation device 10 will be described in detail.
    [062] As shown in figure 8, the separation device 10 comprises a preliminary gas and solids separator 7, a draft damper 15 and a fine gas and solids separator 9 arranged in an order according to the flow direction of the product. The preliminary gas and solids separator 7 is directly in communication with the fluidized bed reactor 4 to receive the product from the fluidized bed reactor 4. The draft damper 15 is arranged vertically and an inlet orifice 16 is arranged in an upper region. 8 of the draft damper 15. A gas outlet 18 of the preliminary gas and solids separator 7 is in communication with the inlet port 16, and a solids outlet 19 of the preliminary gas and solids separator 7 is in communication with a region 6 of the draft damper 15. An outlet orifice 14 is further arranged in the uppermost region 8 of the draft damper 15 in a position offset from the inlet orifice 16. An inlet 20 of the fine gas and solids separator 9 is in communication with the outlet port 14 in the upper region 8 of the draft damper 15 and a solids outlet 21 of the fine gas and solids separator 9 is in communication with the lower region 6 of the draft damper 15.
    [063] In an example as shown in Figure 8, the preliminary gas and solids separator 7 is a cyclone separator and the fine gas and solids separator 9 can also be a cyclone separator. Cyclone separator 7 and cyclone separator 9 may have the same specification or different specifications. In an example, if cyclone separator 9 has different specification than cyclone separator 7, cyclone separator 9 can be selected to be able to separate the particles of smaller particle size when compared to cyclone separator 7.
    [064] During the operation of the separation device 10, the product from the fluidized bed reactor 4 having catalysts loaded therein is fed into the preliminary gas and solids separator 7 first. Most of the catalyst particles are separated from the product in the preliminary gas solids separator 7 and fed into the lower region 6 of the draft damper 15. The product carries the remaining small amount of the catalysts into the higher region 8 from the draft damper 15. The product appropriately slows down in the higher region 8 and enters the fine gas and solids separator 9. The remaining catalysts are separated from the product and fed into the lower region 6 of the draft damper 15. The product is obtained from a gas outlet 22 of the fine gas and solids separator 9.
    [065] Because both the preliminary gas solids separator 7 and the fine gas solids separator 9 can be cyclone separators, the rate of separation of catalysts from the product can be greatly increased. As a result, the product will not experience a side reaction and the final product may contain very few impurities.
    [066] Preferably, the position where the gas outlet 18 of the preliminary gas and solids separator 7 is connected with the draft damper 15 is below a position where the inlet 20 of the fine gas and solids separator 9 is connected with the draft damper 15. As an assembly, the preliminary gas and solids separator 7 is arranged in a lower position and the fine gas and solids separator 9 is arranged in a higher position. In that case, the product from the preliminary gas and solids separator 7 can only move upwards in the uppermost region 8 of the draft damper 15, so as to leave the draft damper 15 and enter the fine gas and solids separator 9. During product movement, the remaining catalysts loaded on it can be precipitated. As a result, the gas and solids separation efficiency can be improved.
    [067] Preferably, the inlet port 16 in the highest region 8 of the draft damper 15 is configured to be tangent to a side wall of the highest region 8. In that case, the product from the fluidized bed reactor 4 can be fed into the higher region 8 on a trajectory that is tangent to the side wall of the higher region 8. As a result, the impact of the product on the draft damper 15 and the higher region 8 can be reduced, so that the vibration of the draft damper 15 can be relieved.
    [068] Draft damper 15 may be a variable diameter container. As shown in Figure 8, the diameter of the upper region 8 of the draft damper 15 is smaller than that of its lower region 6. The ratio of the diameter of the higher region 8 to that of the lower region 6 is in a range from 0.05 to 0.5. For example, the ratio could be 0.08, 0.1, 0.12, or 0.3. As an assembly, the higher region 8 appears to be a tubular piece vertically arranged in the lower region 6. The reason for configuring the above structure for the draft damper 15 is that the upper region 8 can actually function as a flow passage. of the gas rather than a container to accommodate substances, while the lower region 6 can function as a container to accommodate the catalysts. A draft damper 15 with such a structure can have a sedimenter of much smaller diameter than a draft damper 15 in the prior art, thereby the production cost of the apparatus can be reduced.
    [069] In a preferred example, a steam inlet 5 is arranged at a lower end of draft damper 15 and the structure or component (not shown in the drawings) for use in the steam removal operation can be arranged in an interior. of the lower region 6 of the draft damper 15. The structure or component is well known to the person skilled in the art, so it will not be described in detail here. In that case, the lower region 6 of the draft damper 15 can form an extractor, so that the removal of steam can be carried out on the product loaded on the catalysts of the lower region 6 in the process of gas and solids separation, thereby further improving the yield of the product. In a specific example, water steam can be used to remove steam.
    [070] Figure 9 shows a separation device 10' according to example 2 of the present disclosure. Figure 9 does not show a fluidized bed reactor coordinating with the separation device 10'. However, it is easy to understand that the connection mode between the separation device 10' and the fluidized bed reactor is the same as that between the separation device 10 and the fluidized bed reactor as shown in figure 8, which will not be described. in detail.
    [071] The separation device 10' is different from the separation device 10 only in its fine separator of gas and solids. In the separation device 10' as shown in Fig. 9, a fine gas and solids separator 9' comprises two-stage or multi-stage cyclone separators (Fig. 9 merely schematically shows the two stages 91' and 92'). These separators can all be cyclone separators or a combination of multiple types of separators.
    [072] The two or more stages of cyclone separators in series connection are configured so that the input of a first stage cyclone separator 91' is in communication with the highest region 8 of the draft damper 15, the product being obtained from a gas outlet of a second cyclone separator 92'. Furthermore, the gas outlet of the first stage cyclone separator 91' is in communication with the inlet of the second stage cyclone separator 92'. The solids outlets of both the first stage cyclone separator 91' and the second stage cyclone separator 92' are in communication with the lower region 6 of the draft damper 15. It should be noted that the first stage cyclone separator 92' is in communication with the lower region 6 of the draft damper 15. stage 91' is selected to separate relatively large mass catalysts and second stage cyclone separator 92' is selected to separate relatively small mass catalysts. The multi-stage series-connected cyclone separators are similar in structure to the two-stage series-connected cyclone separators, so they will not be described in detail here.
    [073] The effect of separating the catalysts from the product can be improved through said fine gas and solids separator 9', thereby the catalyst recovery efficiency can be improved. In the meantime, the obtained product contains fewer impurities.
    [074] In order to save energy, the feed zone 51 of the catalyst regeneration device 50 is arranged lower than the lowest region 6 of the draft damper 15 and its discharge zone 52 is arranged higher than the inlet zone 70 of the fluidized bed reactor 4, so that gravity can be used to direct the flow of catalysts between the separation device 10, the fluidized bed reactor 4 and the catalyst regeneration device 50. In addition , the lower region 6 of the draft damper 15 is in communication with the supply zone 51 of the catalyst regeneration device 50 through a second pipe 43 and the discharge zone 52 of the catalyst regeneration device 50 is in communication with the inlet zone 70 of the fluidized bed reactor 4 through a third pipe 44. In that case, inactive catalysts can enter the catalyst regeneration device 50 from the draft damper. 15 through the second barrel 43 under gravity and be regenerated in it. The regenerated catalysts automatically enter the fluidized bed reactor 4 from the catalyst regeneration device 50 through the third pipe 44. In the entire process, the catalysts need to be raised only in the catalyst regeneration device 50. Since the catalysts are light , a high pressure gas from the bottom of the catalyst regeneration device 50 is merely required to lift the catalysts. Therefore, the power consumption to drive the flow of catalysts can be greatly reduced and the device can be simplified. Although the second barrel 43 and the third barrel 44 appear to be crossed as shown in Figure 7, in the actual apparatus the second barrel 43 and the third barrel 44 are not crossed, but rather two straight lines in different planes.
    [075] It should be understood that the second pipe 43 is provided with a control valve 46 and the third pipe 44 is provided with a control valve 45 so that the flow of catalysts can be controlled.
    [076] As shown in figure 10 and figure 11, the third pipe 44 is provided with a flow blocking member 47 slanting towards the fluidized bed reactor 4 on top of its inner wall. Fig. 10 shows an example of the flow blocking member 47. According to the example as shown in Fig. 10, the flow blocking member 47 is in the form of a deflector 47. The deflector 47 can effectively block gas and gases. catalysts flowing backwards into the third pipe 44 caused by the strong reaction in the fluidized bed reactor 4, so that the circulation rate of the catalysts can be increased, thereby further increasing the product yield. In a specific example, the ratio of the area of the deflector 47 to a cross-sectional area of the third barrel 44 is in a range of 0.1 to 1, for example, the ratio may be 0.3, 0.45 or 0, 8. In addition, the deflector 47 is sector-shaped or rectangular or even semi-circular. The ratio of the distance between the deflector 47 and the fluidized bed reactor 4 to the length of the third pipe 44 is in a range of 0.01 to 0.5, for example the ratio may be 0.2, 0.3 or 0.4. The angle formed between the deflector 47 and the axis of the third barrel 44 is in a range of 10 to 75 degrees, for example, the angle may be 15 degrees, 10 degrees, 30 degrees or 45 degrees. It should be understood that there may also be a plurality of baffles 47 arranged in parallel as shown by the dashed line in Figure 10.
    [077] Figure 11 shows a flow blocking member 47 according to another example. As shown in Figure 11, the flow blocking member 47 may be configured as a stop bolt projecting radially inwardly from the top of the inner wall of the third barrel 44. There may be a plurality of stop bolts 47 arranged in a row. row along the axis of the third pipe 44. In order to effectively block gas and catalysts flowing backwards from the fluidized bed reactor 4 to the third pipe 44, the ratio of the length of each stop pawl 47 to the diameter of the third barrel 44 is configured in a range of 0.1 to 0.5 and the cross section of each of the stop pawls 47 is in the shape of a triangle, a rectangle or a sector.
    [078] The reaction regeneration apparatus 30 as shown in Figure 7 can be used to prepare aromatic hydrocarbons from oxygenates. Because the preparation of aromatic hydrocarbons requires catalysts with high activity, the catalysts fed into the fluidized bed reactor 4 need to be completely regenerated. A process for preparing aromatic hydrocarbons from oxygenates using the reaction regeneration apparatus 30 will be described in detail.
    [079] Figure 12 schematically shows a reaction regeneration apparatus 30' according to example 2 of the present disclosure. The reaction regeneration apparatus 30' is similar to the reaction regeneration apparatus 30 as shown in figure 7 in the structure. The difference lies only in that the inlet zone 70 of the fluidized bed reactor 4 is arranged lower than the lower region 6 of the draft damper 15 of the separation device 10, and the lower region 6 of the draft damper 15 is in communication with the inlet zone 70 of the fluidized bed reactor 4 through a first pipe 53. The first pipe 53 is also provided with a control valve 54.
    [080] The 30' reaction regeneration apparatus as shown in figure 12 can be used to prepare olefins from oxygenates. Because the preparation of the olefins requires catalysts with moderate activity, the catalysts fed into the fluidized bed reactor 4 must comprise unregenerated catalysts so that the overall activity of the catalysts can be reduced. A process for preparing olefins from methanol using the 30' reaction regeneration apparatus will be described in detail.
    [081] The process for preparing aromatic hydrocarbons will be described based on the reaction regeneration apparatus as shown in Figure 7. Aromatic hydrocarbons are generally prepared from raw material containing oxygenates. For example, oxygenates may comprise one or more selected from the group consisting of methanol, ethanol, n-propyl alcohol, isopropyl alcohol, C4-C20 alcohol, ethyl methyl ether, dimethyl ether, diethyl ether, diisopropyl ether, methane, dimethyl carbonate , acetone and acetic acid. The weight of the oxygenates is responsible for 10 to 100% of the raw material.
    [082] The feedstock containing oxygenates and catalysts reacts in reaction zone 41 of fluidized bed reactor 4. In one example, the catalysts are ZSM-5. The pressure in the fluidized bed reactor 4 indicated by the gauge pressure is in a range of 0 to 0.6 MPa, the average temperature in it is in a range of 440 to 550°C, the space velocity in the reaction zone is in a range from 0.3 to 5 h-1 and the average density in the reaction zone is in a range of 200 to 450 kg/m3. The ratio of the pressure drop generated when raw material flows through dense channel region 61 to that generated when raw material flows through sparse channel region 62 is in a range of 1.2:1 to 10:1 .
    [083] The product obtained and the catalysts loaded into the product are fed into the separation device 10 through the outlet zone 42 of the fluidized bed reactor 4. The operation of the separation device 10 comprises the following steps. First, the product from the fluidized bed reactor 4 having the catalysts loaded into it is preliminarily separated through the preliminary gas and solids separator 7. Next, the product obtained from the preliminary separation carrying the remaining catalysts is fed into the uppermost region 8 from the draft damper 15. Subsequently, the product is withdrawn from the draft damper 15 and fed into the fine gas and solids separator 9 for fine separation. The product is obtained from the gas outlet of the fine gas solids separator 9 and the catalysts of the preliminary gas solids separator 7 and the fine gas solids separator 9 are collected within the lower region 6 of the draft damper 15.
    [084] The catalysts in the lower region 6 of the draft damper 15 are fed into the catalyst regeneration device 50 through the second pipe 43 to be regenerated. In one example, a catalyst regeneration medium is air and the regeneration temperature is in a range of 550 to 650°C.
    [085] The regenerated catalysts are fed into the inlet zone 70 of the fluidized bed reactor 4 through the third pipe 44. Subsequently, the regenerated catalysts can be pushed by the feed gas, such as methanol, into the reaction zone. 41 of fluidized bed reactor 4 again for reaction.
    [086] In a preferred example, the inlet 49 for the accelerator gas is arranged in the outlet zone 42 of the fluidized bed reactor 4. The gas flowing into the outlet zone 42 of the fluidized bed reactor 4 through the inlet 49 to the accelerator gas is water vapor or nitrogen, the linear velocity of the gas being in a range of 1.0 to 10.0 m/s.
    [087] In another preferred example, water vapor is fed into the draft damper 15 from its lower end, so that the product loaded on the catalysts is separated from the catalysts.
    [088] The process to prepare olefins from methanol will be described based on the reaction regeneration apparatus as shown in figure 12. In the reaction regeneration apparatus as shown in figure 12, the inlet zone 70 of the bed reactor fluidized fluid 4 is arranged lower than the lower region 6 of the draft damper 15 and the lower region 6 of the draft damper 15 is in communication with the inlet zone 70 of the fluidized bed reactor 4 through the first pipe 53.
    [089] Methanol and catalysts react in reaction zone 41 of fluidized bed reactor 4. In one example, the catalysts are molecular mesh, such as SAPO-34. The pressure in fluidized bed reactor 4 by gauge pressure is in a range of 0 to 0.4 MPa, the average temperature in it is in a range of 380 to 550°C and the average density in the reaction zone is in a range of 40 to 200 kg/m3. The ratio of the pressure drop generated when raw material flows through dense channel region 61 to that generated when raw material flows through sparse channel region 62 is in a range of 1.2:1 to 10:1 .
    [090] The product obtained and the catalysts loaded into the product are fed into the separation device 10 through the outlet zone 42 of the fluidized bed reactor 4. An operation of the separation device 10 comprises the following steps. First, the product from the fluidized bed reactor 4 having the catalysts loaded into it is preliminarily separated through the preliminary gas and solids separator 7. Next, the product obtained from the preliminary separation carrying the remaining catalysts is fed into the uppermost region 8 from the draft damper 15. Subsequently, the product is withdrawn from the draft damper 15 and fed into the fine gas and solids separator 9 for fine separation. The product is obtained from the gas outlet of the fine gas and solids separator 9, and the catalysts of the preliminary gas and solids separator 7 and the fine gas and solids separator 9 are collected within the lower region 6 of the draft damper 15. .
    [091] A portion of the catalysts in the lower region 6 of the draft damper 15 is fed directly into the inlet zone 70 of the fluidized bed reactor 4 through the first pipe 53. The remaining catalysts are fed into the regeneration device. catalyst 50 through the second pipe 43 to be regenerated. The regenerated catalysts are fed into the inlet zone 70 of the fluidized bed reactor 4 through the third pipe 44 and mixed with the unregenerated catalysts. In one example, a catalyst regeneration medium is air and the regeneration temperature is in a range of 600 to 700°C.
    [092] Subsequently, the catalysts in the inlet zone 70 can be pushed by the feed gas, such as methanol, into the reaction zone 41 of the fluidized bed reactor 4 again for reaction.
    [093] In a preferred example, the inlet 49 for the accelerator gas is arranged in the outlet zone 42 of the fluidized bed reactor 4. The gas flowing into the outlet zone 42 of the fluidized bed reactor 4 through the inlet 49 to the accelerator gas is water vapor or nitrogen, the linear velocity of the gas being in a range of 1.0 to 10.0 m/s.
    [094] In another preferred example, water vapor is fed into draft damper 15 from its lower end, so that product loaded onto the catalysts can be separated from the catalysts.
    [095] The inventor performed the example for preparing aromatic hydrocarbons using the process according to the present disclosure and the reaction regeneration apparatus as shown in figure 12 and made a comparison with the process for preparing aromatic hydrocarbons in the prior art. In the examples, the raw materials and catalysts for each experiment are the same and the experiment parameters are conventional parameters for the reaction. Relevant data for the reaction regeneration apparatus and product yield are given in Table I. Table I

    [096] As shown in Table I, according to the reaction regeneration apparatus and process of the present disclosure, the yield of aromatic hydrocarbons can be remarkably increased. For example, the yield of aromatic hydrocarbons can be increased by a maximum of 5%, which is a huge improvement for chemical enterprises with high production.
    [097] While the present disclosure has been described in view of preferred embodiments, various modifications and variations on the present disclosure can be made by one of ordinary skill in the art without departing from the scope and spirit of the present disclosure. In particular, as long as there is no structural conflict, various modalities as well as the respective technical aspects mentioned herein may be combined with each other in any way. The present disclosure is not limited to the specific examples disclosed herein, but preferably includes all technical solutions that fall within the scope of the claims.
    权利要求:
    Claims (34)
    [0001]
    1. Fluidized bed reactor, comprising an inlet zone (70) in a lower position, an outlet zone (42) in a higher position and a reaction zone (41) between the inlet zone (70) and the outlet zone (71), wherein a guide plate (48) is arranged in the reaction zone (41), comprising a dense channel region (61) in an intermediate region thereof and a sparse channel region (62) disposed at a periphery thereof encompassing the dense channel region (61); CHARACTERIZED in that an inlet for the accelerator gas (49) is arranged in the outlet zone (42) of the fluidized bed reactor (4).
    [0002]
    2. Fluidized bed reactor, according to claim 1, CHARACTERIZED by the fact that a dimension of a channel in the dense channel region (61) is smaller than that of a channel in the sparse channel region (62), in that a ratio of the dimension of the channel in the dense channel region (61) to that of the channel in the sparse channel region (62) is in a range of 1:4 to 2:3.
    [0003]
    3. Fluidized bed reactor, according to claim 2, CHARACTERIZED by the fact that the dimension of the channel in the dense channel region (61) is in a range of 0.01 to 0.08 m.
    [0004]
    4. Fluidized bed reactor according to any one of claims 1 to 3, CHARACTERIZED in that each of the dense channel region (61) and the sparse channel region (62) comprises a circular plate having equally distributed pores , or a plurality of separate concentric ring-shaped angled panels (65) or a plurality of separate straight panels (69) in parallel.
    [0005]
    5. Fluidized bed reactor, according to any one of claims 1 to 4, CHARACTERIZED by the fact that the dense channel region (61) is round in shape and the sparse channel region (62) is annular-ring shaped , and a ratio of a diameter of the dense channel region (61) to a width of the sparse channel region (62) is in a range of 2:1 to 9:1.
    [0006]
    6. Fluidized bed reactor according to any one of claims 1 to 5, CHARACTERIZED in that a plurality of guide plates (48) are provided, which are distributed along an axial direction of the fluidized bed reactor ( 4).
    [0007]
    7. Fluidized bed reactor, according to claim 1, CHARACTERIZED by the fact that the inlet for the accelerator gas (69) is configured to extend obliquely from a lower position to a higher position.
    [0008]
    Reaction regeneration apparatus, comprising the fluidized bed reactor (4) as defined in any one of claims 1 to 7, and further comprising a separation device (10) and a catalyst regeneration device (50) respectively connected. with the fluidized bed reactor (4), CHARACTERIZED in that the separation device (10) comprises a preliminary gas and solids separator (7) in communication with an outlet zone (42) of the fluidized bed reactor (4) ); a vertically arranged draft damper (15), a lower region (6) of the draft damper (15) being in communication with a solids outlet (19) of the preliminary gas solids separator (7) to collect catalyst particles and an uppermost region (8) of the draft damper (15) being in communication with a gas outlet (18) of the preliminary gas and solids separator (7); and a fine gas and solids separator (9), an inlet (20) of the fine gas and solids separator (9) being in communication with the uppermost region (8) of the draft damper (15) and a solids outlet (21) its being in communication with the lower region (6) of the draft damper (15), and the catalyst regeneration device (50) comprises a supply zone (51) in a lower position and a discharge (52) in a higher position, the feed zone (51) being arranged lower than the lower region (6) of the draft damper (15) and the discharge zone (52) being arranged higher than the that the inlet zone (70) of the fluidized bed reactor (4), wherein the lower region (6) of the draft damper (15) is in communication with the feed zone (51) of the catalyst regeneration device (50) through a second pipe (43), and the discharge zone (52) of the catalyst regeneration device (50) is in communication with the and inlet (70) of the fluidized bed reactor (4) through a third pipe (44).
    [0009]
    9. Reaction regeneration apparatus, according to claim 8, CHARACTERIZED by the fact that a diameter of the highest region (8) of the draft damper (15) is smaller than that of its lowest region (6).
    [0010]
    10. Reaction regeneration apparatus, according to claim 8 or 9, CHARACTERIZED by the fact that both the preliminary gas and solids separator (7) and the fine gas and solids separator (9) are cyclone separators.
    [0011]
    11. Reaction regeneration apparatus, according to claim 8 or 9, CHARACTERIZED by the fact that the preliminary gas and solids separator (7) is a cyclone separator, and the fine gas and solids separator (9) comprises two-stage or multi-stage series cyclone separators, where two-stage or multi-stage series cyclone separators are configured so that an input of a first-stage cyclone separator is in communication with the highest region ( 8) of the draft damper (15), the gas product being obtained from a gas outlet of a cyclone separator of the last stage, a gas outlet of an upstream cyclone separator is in communication with an inlet of a separator downstream cyclone and the solids outlets of all cyclone separators are in communication with the lowest region (6) of the draft damper (15).
    [0012]
    12. Reaction regeneration apparatus, according to any one of claims 8 to 11, CHARACTERIZED by the fact that the lower region (6) of the draft damper (15) is configured and arranged so that it performs an operation flow extraction.
    [0013]
    13. Reaction regeneration apparatus, according to claim 8, CHARACTERIZED by the fact that the third pipe (44) is provided with a flow blocking member (47) at a top of an internal wall thereof.
    [0014]
    14. Reaction regeneration apparatus, according to claim 13, CHARACTERIZED by the fact that the flow blocking member (47) is an inclined deflector for the fluidized bed reactor (4).
    [0015]
    15. Reaction regeneration apparatus according to claim 14, CHARACTERIZED in that a plurality of baffles are provided, which are arranged in parallel with respect to each other.
    [0016]
    16. Reaction regeneration apparatus according to claim 13, CHARACTERIZED in that the flow blocking member is a radially inwardly projecting stop tongue.
    [0017]
    17. Reaction regeneration apparatus according to claim 16, CHARACTERIZED in that a plurality of stop pawls are provided, which are arranged in a row along a geometric axis of the third barrel (44).
    [0018]
    18. Reaction regeneration apparatus, according to claim 17, CHARACTERIZED by the fact that a ratio of a length of each stop pawl to a diameter of the third barrel (44) is in a range from 0.1 to 0, 5.
    [0019]
    19. Reaction regeneration apparatus, according to any one of claims 8 to 18, CHARACTERIZED by the fact that the inlet zone (70) of the fluidized bed reactor (4) is arranged lower than the lowest region ( 6) of the draft damper (15) of the separation device (10) and the lower region (6) of the draft damper (15) is in communication with the inlet zone (70) of the fluidized bed reactor (4) through a first pipe (53).
    [0020]
    A process for preparing olefins, using a reaction regeneration apparatus as defined in claim 8, wherein an inlet zone (70) of a fluidized bed reactor (4) is arranged lower than a lower region ( 6) of a draft damper (15) of a separation device (10), and the lower region (6) of the draft damper (15) is in communication with the inlet zone (70) of the fluidized bed reactor (4) through a first pipe (53), CHARACTERIZED by the fact that the process comprises: reacting gaseous raw material containing oxygenates with catalysts in a reaction zone (41) of the fluidized bed reactor (4); feeding the product obtained and the catalysts loaded into the separation device (10) through an outlet zone (42) of the fluidized bed reactor (4); separating the product from the loaded catalysts through the separation device (10), feeding a portion of the catalysts obtained from the separation directly into the inlet zone (70) of the fluidized bed reactor (4), subsequently regenerating the remaining catalysts and feeding the regenerated catalysts into the inlet zone (70) of the fluidized bed reactor (4), and mixing the unregenerated catalysts and the regenerated catalysts in the inlet zone (70) of the fluidized bed reactor (4) and then feeding the catalysts mixed into the reaction zone (41) of the fluidized bed reactor (4).
    [0021]
    21. Process, according to claim 20, CHARACTERIZED by the fact that a weight ratio of unregenerated catalysts in relation to regenerated catalysts is in a range of 0.3 to 1.5.
    [0022]
    22. Process according to claim 20 or 21, CHARACTERIZED in that an operation of the separation device (10) comprises: preliminarily separating the product from the fluidized bed reactor (4) having catalysts loaded into it through a preliminary separator of gas and solids (7), feed the product obtained from the preliminary separation, loading the remaining catalysts into a higher region (8) of the draft damper (15), take the gas product out of the draft damper (15) ) and feed it into a fine gas and solids separator (9) for fine separation, and obtain the final gas product from a gas outlet of the fine gas and solids separator (9) and collect the catalysts from the preliminary gas and solids separator (7) and the fine gas and solids separator (9) into the lower region (6) of the draft damper (15).
    [0023]
    23. Process according to claim 22, CHARACTERIZED by the fact that water vapor is fed into the draft damper (15) from its lower end, so that the product loaded on the catalysts is separated of the catalysts.
    [0024]
    24. Process according to any one of claims 20 to 23, CHARACTERIZED by the fact that a pressure in the fluidized bed reactor (4) by the gauge pressure is in a range of 0 to 0.4 MPa, an average temperature in it is in a range of 380 to 550°C and an average density in the reaction zone is in a range of 40 to 200 kg/m3, and the catalyst used in it is SAPO-34, in which a catalyst regeneration medium is the air and a regeneration temperature is in a range of 600 to 700°C.
    [0025]
    25. Process, according to claim 20, CHARACTERIZED by the fact that a ratio of a pressure drop generated when the gaseous raw material flows through the dense channel region (61) to that generated when the gaseous raw material flows across the sparse channel region (62) is in a range of 1.2:1 to 10:1.
    [0026]
    26. Process, according to claim 24 or 25, CHARACTERIZED by the fact that an inlet for the accelerator gas (49) is arranged in the outlet zone (42) of the fluidized bed reactor (4), and the gas flowing to within the outlet zone (42) of the fluidized bed reactor (4) through the inlet to the accelerator gas (49) is water vapor or nitrogen, a linear velocity of the gas being in a range of 1.0 to 10.0 m/s
    [0027]
    27. Process according to any one of claims 20 to 26, CHARACTERIZED in that the oxygenates comprise one or more selected from a group consisting of methanol, ethanol, n-propyl alcohol, isopropyl alcohol, C4-C20 alcohol, ethyl methyl ether, dimethyl ether, diethyl ether, diisopropyl ether, methanal, dimethyl carbonate, acetone and acetic acid and a weight of the oxygenates is responsible for 10 to 100% of the raw material.
    [0028]
    28. Process for the preparation of aromatic hydrocarbons, using a reaction regeneration apparatus as defined in claim 8, CHARACTERIZED by the fact that the process comprises: reacting raw material containing oxygenates with catalysts in a reaction zone (41) of a fluidized bed reactor (4); feeding the obtained product and the catalysts loaded therein into a separation device (10) through an outlet zone (42) of the fluidized bed reactor (4), and separating the product from the catalysts loaded therein in the separation device ( 10), regenerating the catalysts obtained from the separation and feeding the regenerated catalysts into the inlet zone (70) of the fluidized bed reactor (4) and subsequently into the reaction zone (41) of the fluidized bed reactor (4) .
    [0029]
    29. Process according to claim 28, CHARACTERIZED by the fact that an operation of the separation device (10) comprises: preliminarily separating the product from the fluidized bed reactor (4) having the catalysts loaded into it through a preliminary separator of gas and solids (7), feed the producer obtained from the preliminary separation by loading the remaining catalysts into a higher region (8) of the draft damper (15), take the product out of the draft damper (15) and feed the product into a fine gas and solids separator (9) for fine separation; and obtaining the final product from a gas outlet from the fine gas and solids separator (9) and collecting the catalysts from the preliminary gas and solids separator (7) and the fine gas and solids separator (9) into the lower region. (6) of the draft damper (15).
    [0030]
    30. Process, according to claim 29, CHARACTERIZED by the fact that water vapor is fed into the draft damper (15) from its lower end, so that the product loaded on the catalysts is separated of the catalysts.
    [0031]
    31. Process according to any one of claims 28 to 30, CHARACTERIZED by the fact that a pressure in the fluidized bed reactor (4) by the gauge pressure is in a range of 0 to 0.6 MPa, an average temperature in it is in a range of 440 to 550°C, a space velocity in the reaction zone is in a range of 0.3 to 5 h-1 and an average density in the reaction zone is in a range of 200 to 450 kg/m3 and the catalyst used in it is ZSM-5, where the catalyst regeneration medium is air and a regeneration temperature is in a range of 550 to 650°C.
    [0032]
    32. Process, according to claim 28, CHARACTERIZED by the fact that a ratio of the pressure drop generated when the gaseous raw material flows through the dense channel region (61) to that generated when the gaseous raw material flows through of the sparse channel region (62) is in a range of 1.2:1 to 10:1.
    [0033]
    33. Process, according to claim 31 or 32, CHARACTERIZED by the fact that an inlet for the accelerator gas (49) is arranged in the outlet zone (42) of the fluidized bed reactor (4), and the gas flowing to within the outlet zone (42) of the fluidized bed reactor (4) through the inlet to the accelerator gas (49) is water vapor or nitrogen, a linear velocity of the gas being in a range of 1.0 to 10.0 m/s
    [0034]
    34. Process according to any one of claims 28 to 33, CHARACTERIZED in that the oxygenates comprise one or more selected from a group consisting of methanol, ethanol, n-propyl alcohol, isopropyl alcohol, C4-C20 alcohol, ethyl methyl ether, dimethyl ether, diethyl ether, diisopropyl ether, methanal, dimethyl carbonate, acetone and acetic acid and a weight of the oxygenates is responsible for 10 to 100% of the raw material.
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    RU2015144094A|2017-04-19|
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    法律状态:
    2018-01-09| B12F| Other appeals [chapter 12.6 patent gazette]|
    2019-12-03| B150| Others concerning applications: publication cancelled [chapter 15.30 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 15.21 NA RPI NO 2439 DE 03/10/2017 POR TER SIDO INDEVIDA. |
    2020-01-28| B03A| Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]|
    2020-05-05| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-12-29| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|
    2021-12-21| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2022-02-15| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/10/2015, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    CN201410539938|2014-10-14|
    CN201410539938.0|2014-10-14|
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